XiMo - Olefin Metathesis Highlights

Stereoretentive Catalytic Olefin Metathesis. In Situ Methylene Capping 07. August, 2017 In situ methylene capping: A general strategy for efficient stereoretentive catalytic olefin metathesis is developed using Ru dithiolate catalysts. The concept, methodological implications, and applications to synthesis of biologically active compounds is described.
Direct Synthesis of Z-Alkenyl Halides through Catalytic Cross-Metathesis 22. February, 2017 Here we show that previously unknown halo-substituted molybdenum alkylidene species are exceptionally reactive and are able to participate in high-yielding olefin metathesis reactions that afford acyclic 1,2-disubstituted Z-Alkenyl halides.
Molybdenum chloride catalysts for Z-selective olefin metathesis reactions 17. January, 2017 A transformative advance in chemistry has been the development of catalyst-controlled stereoselective olefin metathesis reactions; the original discovery, disclosed in 2009, and many of the subsequent related breakthroughs have been the result of research carried out in the laboratories of Professor Amir Hoveyda.

Stereoretentive Catalytic Olefin Metathesis. In Situ Methylene Capping

07. August, 2017

In situ methylene capping: A general strategy for efficient stereoretentive catalytic olefin metathesis is developed using Ru dithiolate catalysts. The concept, methodological implications, and applications to synthesis of biologically active compounds is described.

Direct Synthesis of Z-Alkenyl Halides through Catalytic Cross-Metathesis

22. February, 2017

Here we show that previously unknown halo-substituted molybdenum alkylidene species are exceptionally reactive and are able to participate in high-yielding olefin metathesis reactions that afford acyclic 1,2-disubstituted Z-Alkenyl halides.

Molybdenum chloride catalysts for Z-selective olefin metathesis reactions

17. January, 2017

A transformative advance in chemistry has been the development of catalyst-controlled stereoselective olefin metathesis reactions; the original discovery, disclosed in 2009, and many of the subsequent related breakthroughs have been the result of research carried out in the laboratories of Professor Amir Hoveyda.

Stereoretentive Catalytic Olefin Metathesis. In Situ Methylene Capping

Direct Synthesis of Z-Alkenyl Halides through Catalytic Cross-Metathesis

Molybdenum chloride catalysts for Z-selective olefin metathesis reactions

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