Ring-Opening Metathesis Polymerization

30. March, 2017

It has been shown that Z-selective reactions in ROMP have some generality and that syndiotacticity (for cis polymers) is predictable as a consequence of the mechanism through which MAP catalysts operate, i.e., inversion of configuration at the metal center with each forward metathesis step (stereogenic metal control).

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Efficient Synthesis of Metathesis Catalysts

07. March, 2017

Despite the lack of literature precedents, Mo and W based metathesis catalysts excel in extreme low catalyst loadings. Feedstock quality granted loadings of 6 – 50 ppm (by mole) are common.

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