Ring-Opening Metathesis Polymerization
30. March, 2017It has been shown that Z-selective reactions in ROMP have some generality and that syndiotacticity (for cis polymers) is predictable as a consequence of the mechanism through which MAP catalysts operate, i.e., inversion of configuration at the metal center with each forward metathesis step (stereogenic metal control).
Read moreEfficient Synthesis of Metathesis Catalysts
07. March, 2017Despite the lack of literature precedents, Mo and W based metathesis catalysts excel in extreme low catalyst loadings. Feedstock quality granted loadings of 6 – 50 ppm (by mole) are common.
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