Activation of Oxo Tungsten Complexes
12. April, 2017The coordination of B(C6F5)3to an oxo ligand in tungsten oxo alkylidene bis(aryloxide) complexes, where the aryloxide is O-2,6-(mesityl) 2C6H3 (HMTO) or 2,6-diadamantyl-4-methylphenoxide (dAdPO), accelerates the formation of metallacyclobutane complexes from alkylidenes as well as the rearrangement of metallacyclobutane complexes.
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