Direct Synthesis of Z-Alkenyl Halides through Catalytic Cross-Metathesis
22. February, 2017Here we show that previously unknown halo-substituted molybdenum alkylidene species are exceptionally reactive and are able to participate in high-yielding olefin metathesis reactions that afford acyclic 1,2-disubstituted Z-Alkenyl halides.
Read moreKinetically Controlled E-Selective Catalytic Olefin Metathesis
13. February, 2017A significant shortcoming in olefin metathesis, a chemical process that is central to research in several branches of chemistry, is the complete lack of efficient methods that kinetically favor E-isomers in the product distribution.
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